
Angelina Jolie and Brad Pitt
The actors “fell in love” on the set of Mr. & Mrs. Smith in 2005, according to Angelina. Pitt and ex-wife Jennifer Aniston officially divorced that year as news of his relationship with Jolie made headlines. The two were married in 2014, and have six children together: Maddox, Pax, Zahara, Shiloh, Vivenne, and Knox.

Jennifer Aniston and Justin Theroux
Wanderlust co-stars Theroux and Aniston began dating in 2011, and got engaged in 2012 before making it official in August 2015 during a small ceremony at their California home.
Image Credit: Gemma La Mana; Axelle/Bauer-Griffin/FilmMagic

Jennifer Garner and Ben Affleck
The two first met on the set of Pearl Harbor back in 2001, and would work together again two years later on the superhero flick Daredevil. Affleck and Garner were married in 2005 and would go on to have three children: Violet, Seraphina, and Samuel. They announced their split in June 2015 after 10 years together.

Alexis Bledel and Vincent Kartheiser
The Mad Men co-stars first made their relationship public back in Oct. 2012 and were engaged just a few months later in Feb. 2013. Of course, Bledel’s Gilmore Girls’ TV mom (Lauren Graham) gave the seal of approval saying she was “very happy for them.” The two made it official in June 2014, saying “I do” during a small ceremony in California.

Anna Paquin and Stephen Moyer
The Oscar-winning actress met her husband on the set of HBO’s vampire drama True Blood as the two played on-again-off-again love interests Sookie Stackhouse and Bill Compton. After a year-long engagement, they were married in Aug. 2010. They have two children together: Twins Charlie and Poppy.
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